Product ID:CROSS LINK COLORSTABLE SELF CURING MONOMER
MSDS Date:04/14/1987
FSC:NIIN:Submitter:F BT
Status Code:A
MSDS Number: CKXCW

FRICKE DENTAL MFG CO INC

208 WEST RIDGE ROAD
VILLA PARK, IL 60181
US

Emergency Phone: 312-833-2627

Info Phone: 312-833-2627

Cage: 0K9H1

FRICKE DENTAL MFG CO INC

VILLA PARK, IL 60181 US

Telephone: 312-833-2627

Cage: 0K9H1

METHYL METHACRYLATE

CAS: 80-62-6

RTECS: OZ5075000

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYLENE GLYCOL DIMETHACRYLATE

CAS: 97-90-5

RTECS: OZ4400000

OSHA PEL NE

ACGIH TLV: 2 PPM

DIMETHYL-P-TOLUIDINE

CAS: 99-97-8

RTECS: XU5803000

HYDROQUINONE

CAS: 123-31-9

RTECS: MX3500000

Fraction By Weight: <70% PPM

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Explanation of Carcinogenicity:UNDER SOME CIRCUMSTANCES, MUTAGENIC
CHANGES HAVE BEEN OBSERVED WITH MMA. THE MEANING AND SIGNIFICANCE
OF THESE RESULTS IS NOT UNDERSTOOD. AT 1000 PPM, IS WEAKLY
EMBRYOTOXIC WITH RATS.
Effects of Overexposure:INHALATION: OVEREXPOSURE MAY CAUSE EYE, NOSE
AND THROAT IRRITATION. MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS
SUCH AS DIZZINESS, HEADACHE, NAUSEA, AND LOSS OF CONCIOUSNESS.
SKIN OR EYE: VAPOR MAY CA USE IRRITATION OF THE EYES, LIQUID MAY
CAUSE CORNEAL INJURY. REPEATED OR PROLONGED CONTACT MAY CAUSE
ALLERGIC SKIN RASH, ITCHING, SWELLING. POTENTIAL SKIN SENSITIZER.

First Aid:INGESTION: INDUCE VOMITING AND GET PROMPT MEDICAL ATTENTION.
INHALATION: REMOVE TO FRESH AIR. IF HAVING BREATHING DIFFICULTY,
ADMINISTER OXYGEN. IF NOT BREATHING, ADMINISTER ARTIFICIAL
RESPIRATION. CALL A PHYSICIAN. IN CASE OF EYE CONTACT, FLUSH
EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IN CASE OF SKIN
CONTACT, WASH WITH SOAP AND WATER.

Flash Point Method:TOC
Flash Point:=12.8C, 55.F
Lower Limits:2%
Upper Limits:10%
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG
Fire Fighting Procedures:WEAR RESPIRATOR-MSHA/NIOSH-APPROVED OR
EQUIVALENT, SELF CONTAINED BREATHING APPARATUS. USE COLD WATER
SPRAY TO COOL CONTAINERS. HEAT CAN CAUSE CONTAINERS TO RUPTURE
EXPLOSIVELY DUE TO POLYMERIZATION . VAPORS ARE HEAVIER THAN AIR
AND MAY TRAVEL TO IGNITION SOURCE.

Spill Release Procedures:EVACUATE AREA. REMOVE SOURCES OF IGNITION.
PREVENT SKIN CONTACT AND BREATHING OF VAPOR. CONFINE AND REMOVE
WITH INERT ABSORBANT. VENTILATE AREA.

Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY
FROM HEAT, DIRECT SUNLIGHT, SPARKS, AND FLAME. CLOSE CONTAINER
AFTER EACH USE.

Respiratory Protection:WHEN LEVELS EXCEED 100 PPM, WEAR SELF CONTAINED
BREATHING APPARATUS.
Ventilation:PROVIDE SUFFICIENT VENTILATION TO KEEP LEVELS BELOW 100
PPM.
Protective Gloves:NEOPRENE
Eye Protection:SPLASHPROOF GOGGLES
Other Protective Equipment:NEOPRENE BOOTS AND COVERALLS. EYEWASH AND
EMERGENCY SHOWER SHOUDL BE AVAILABLE.
Supplemental Safety and Health

Boiling Pt:=101.1C, 214.F
Vapor Pres:29MM
Vapor Density:3.5
Evaporation Rate & Reference:3
Solubility in Water:1.5 GMS/100 GMS
Appearance and Odor:CLEAR, PALE YELLOW LIQUID; ACRID FRUITY ODOR
Percent Volatiles by Volume:90%

Stability Indicator/Materials to Avoid:YES
REDUCING AND OXIDIZING AGENTS. MATERIAL HAS STRONG SOLVENT PROPERTIES
AND CAN SOFTEN PAINT OR RUBBER.
Stability Condition to Avoid:HEAT AND IGNITION SOURCES. CONTAMINATION.
Hazardous Decomposition Products:CAN YIELD CO, CO2, SMOKE.
Conditions to Avoid Polymerization:EXCESSIVE HEAT, PEROXIDES, AMINES.

Waste Disposal Methods:EPA LISTED HAZARDOUS WASTE UNDER RCRA (U-162).
DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEMS.
INCINERATE IN A FACILITY WHICH COMPLIES WITH FEDERAL, STATE AND
LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Transport Information:US DOT, IATA, RID/ADR, IMO, CANADA TDG: NO INFO
AVAIL. --ECOLOGICAL INFO: OEL-RUSSIA: STEL 0.5 PPM (1 MG/M3)
(DUST). OEL-SWEDEN: TWA 0.2 MG/M3 (RESP DUST). OEL-SWEDEN: TWA 0.2
MG/M3 (FUME). OEL-SWEDEN : TWA 1 MG/M3 (TOTAL DUST).
OEL-SWITZERLAND: TWA 0.1 MG/M3; STEL 0.2 MG/M3 (FUME).
OEL-SWITZERLAND: TWA 1 MG/M3; STEL 1 MG/M3. OEL-THAILAND: TWA 0.1
MG/M3 (FUME). OEL-THAILAND: TWA 1 MG/M3. OEL-UNITED KINGDOM: TWA
0.2 MG/M3 (FUME). OEL-UNITED KINGDOM: TWA 1 MG/M3. OEL IN BULGARIA,
COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV.

SARA Title III Information:SECTION 302 (RQ) CAS #7440-50-8: FINAL RQ =
5000 LBS (2270 KG) (NO REPORTING OF RELS). SECTION 302 (TPQ) NONE
OF CHEMS IN PROD HAVE TPQ. SARA CODES: CAS #7440-50-8: ACUTE,
CHRONIC, FLAM. SECTION 313: THIS MATL CNTNS COPPER (#7440-50-8,
100%) WHICH IS SUBJECT TO REPORTING REQS OF SECTION 313 OF SARA
TITLE III & 40 CFR PART 373.
Federal Regulatory Information:CAS #7440-50-8 IS LISTED ON TSCA
INVENTORY. NONE OF CHEMS ARE ON HLTH & SFTY REPORTING LIST. NONE OF
CHEMS IN PROD ARE UNDER CHEM TEST RULE. NONE OF CHEMS ARE LISTED
UNDER TSCA SECTION 12B. NONE OF CH EMS IN MATL HAVE SNUR UNDER
TSCA. EUROPEAN/INTERNATL REGS - EUROPEAN LABELING I/A/W EC
DIRECTIVES HAZ SYMBOLS: NOT AVAIL. WGK (WATER DANGER/PROT) CAS
#7440-50-8: 0. CANADA - CAS #7440-50-8 IS LISTED O N CANADA'S
DSL/NDSL LIST. PROD HAS WHMIS CLASSIFICATION OF D2B. IT IS NOT
LISTED ON CANADA'S INGRED DISCLOSURE LIST. EXPOS LIMS: CAS
#7440-50-8: OEL-ARAB REPUBLIC OF EGYPT: TWA 0.1 MG/M3 (FUME).
OEL-AUSTRALIA: (TOXICOLOGICAL INFO)
State Regulatory Information:CAS #7440-50-8 CAN BE FOUND ON FOLLOWING
STATE RIGHT TO KNOW LISTS: CA, NJ, FL, PA, MN, MA. CALIFORNIA NO
SIGNIFICANT RISK LEVEL: NONE OF CHEMS IN THIS PROD ARE LISTED.